Thomas H. Epps, III, the Allan & Myra Ferguson Distinguished Professor of Chemical & Biomolecular Engineering and Professor of Materials Science & Engineering at the University of Delaware, will deliver a seminar entitled, "From Waste to Polymers: Creating Sustainable Materials from Biomass." Dr. Epps is also Director of the Center for Research in Soft Matter & Polymers (CRiSP), Director of the Center for Hybrid, Active, and Responsive Materials (CHARM) - NSF MRSEC, and Deputy Director of the Center for Plastics Innovation (CPI) - DOE EFRC. This seminar is co- hosted by NYU Professor of Chemistry Marcus Weck and Professor Iwao Teraoka of the NYU Tandon School of Engineering.
For more information about Thomas Epps, click here.
Zoom Link: https://nyu.zoom.us/j/98045151289?pwd=bzg5cmpVY000ZXVpMjZONlVIL09yUT09
Abstract: Economic challenges continue to hamper the adoption of biobased polymers as alternatives to petroleum-based plastics. Generally, renewable polymers are too expensive due to the inherent variability in biobased feedstocks and the significant separation steps required to make purified monomer streams. Here, we demonstrate that materials with reproducible thermal and mechanical characteristics can be synthesized in a controlled and predictable manner from batches of monomers with complex and somewhat variable compositions, such as minimally processed bio-oils obtained from depolymerized lignin. As one example, we leveraged polymer structure-property relationships to fabricate high-performance pressure sensitive adhesives (PSAs) from compounds directly obtained from raw biomass (poplar wood) deconstruction. These PSAs, generated from biobased block copolymers, exhibited the nanoscale characteristics of conventional phase-separated materials and had peel forces and tack forces that were competitive with commercial tapes. As another example, we investigated the thermomechanical and environmental toxicity behavior of newly created bisguaiacol precursors and epoxy networks, for which the precursor compounds could be derived from lignin. These systems demonstrated drop-in potential, in both synthesis and materials properties, relative to petroleum-based analogues, yet most importantly, demonstrated reduced negative environmental impacts when screened by several common toxicity assays. In the above cases we employed raw biomass as our feedstock; however, we have recently demonstrated the versality of our strategy by expanding our feedstocks to other commercial scale inputs and waste streams.